MSE PRO Dichloro[bis(diphenylphosphinophenyl)ether]palladium(II) (DPEPhosPdCl2) is an important organometallic palladium complex widely employed as a catalyst in various organic transformations, particularly in cross-coupling reactions. DPEPhosPdCl2 is a widely used catalyst precursor in various cross-coupling reactions, including Suzuki, Heck, Sonogashira, and Buchwald-Hartwig amination. It serves as a source of the active palladium(0) species, which are generated in situ under the reaction conditions and facilitate the formation of new carbon-carbon or carbon-heteroatom bonds.
MSE Supplies offers various catalysts and ligands of coupling reaction. Please contact us for customization or bulk orders.
CAS No. | 205319-06-8 |
Chemical name | Dichloro[bis(diphenylphosphinophenyl)ether]palladium(II) |
Synonym(s) |
|
Chemical formula | C36H28Cl2OP2Pd |
Pack size | 5 g (CM1403) 25 g (CM1404) |
Molecular weight | 715.88 g/mol |
Purity | 98.0% |
Melting point | 243-250 C |
Solubility | Insoluble in water |
Appearance | Light yellow to yellow solid |
Storage temperature | 2-8C, protect from light, stored under nitrogen |
[1] Bennett, J., Doyle, R. J., Lee, H. Y., Lu, D., Salem, G., Speldewinde, D. J., ... & Willis, A. C. (2010). Synthesis of 1, 3-azaphosphol-2-ones. Crystal and molecular structures of [SP-4-2]-dichlorobis (3-phenyl-1, 3-dihydrobenzo [1, 3] azaphosphol-2-one-P) palladium (II) and its chloro (methyl) platinum (II) analogue.Dalton Transactions,39(1), 256-264.
[2] Segapelo, T. V., Lillywhite, S., Nordlander, E., Haukka, M., & Darkwa, J. (2012). Palladium (II), platinum (II) and gold (I) complexes containing chiral diphosphines of the Josiphos and Walphos familiesSynthesis and evaluation as anticancer agents.Polyhedron,36(1), 97-103.